Absorption and stripping in addition to the distillation, there are other unit operations used for separating substances absorption is the unit operation in which one or more components of a gas stream are removed from the gas mixture by being absorbed onto a nonvolatile liquid called a solvent in this case, the solvent is the separating. Adsorption is a mass transfer operation in that a constituent in liquid phase is transferred to the solid phase. Adsorption is a surfacebased process where a film of adsorbate is created on the surface while absorption involves the entire volume of the absorbing substance. Usually, the shape must be determined experimentally.
New opportunities for solar adsorption refrigeration. There is scarcely any industrial process that does not require a preliminary purification of raw materials or final separation of products. This can be measured simply using a graduated cylinder. Adsorption and membrane processes are also depapproved treatment technologies. The wave front may change shape as it moves through the bed, and the mass transfer zone may broaden or diminish. Mass transfer operations i introduction video youtube. The basic principle of operation for carbon adsorption is the mass transfer and adsorption of a molecule from a. Binary mass transfer in stagnant systems and in laminar flow 5. This course will provide an overview on mass transfer at basic to an. The adsorbate is the substance that is being removed from the liquid phase at the interface. The mass transfer zone width and shape depends on the adsorption isotherm, flow rate, mass transfer rate to the particles, and diffusion in the pores. Absorption and extraction jose coca, salvador ordonez, and eva diaz department of chemical engineering and environmental technology, university of oviedo, oviedo, spain keywords. Heat and mass transfer nptel online videos, courses. Modeling gas absorption worcester polytechnic institute.
Introduction to absorption, equilibrium in gasliquid system, and minimum liquid rate duration. Moreover, chemical adsorption also exhibits the phenomena of salt swelling and agglomeration, which are critical to heat and mass transfer performance. The flux relationships are integrated across the film yielding analytical. One of the most common and rapidly developing systems used to carry out the absorption process on an industrial scale is the packed tower. Absorption vs adsorption difference and comparison diffen. Because the forces are not strong, the adsorption may be easily reversed. An industrial wastewater contains 10 mgl chlorophenol, and. Dryingmechanism treybal, mass transfer operations 655661 4. Requirements on mass transfer have to be considered in the design of electrochemical reactors, such as the composition, configuration, and control of electrolyte systems. Jul 02, 2014 lecture series on heat and mass transfer by prof. In fact, development in masstransfer theory closely follows that in heat transfer, with the pioneering works of lewis and whitman in 1924 already proposing a masstransfer coefficient.
This course applies the concepts of diffusion mass and interphase transfer to the analysis of different unit operations such as humidification, drying, adsorption, extraction, crystallization leaching, and membrane processes. Therefore, a mass transfer model for adsorption filters had to be developed to predict the decay in filter efficiency over time as a function of the bed properties, the air flow rate, and the adsorbentadsorbate system characteristics. The basic principle of operation for carbon adsorption is the mass transfer and adsorption of a molecule from a liquid or gas into solid surface. Particle density is the mass of adsorbent per volume occupied by the particle. Rate and equilibrium stage based modeling approaches. An approximate rate equation based on a filmmodel representation of diffusional mass transfer has been developed to describe the kinetics of multicomponent adsorption. Design by masstransferzone concept, chemical engineering, 1973. Mass transfer ii nptel online videos, courses iit video. In fact, development in mass transfer theory closely follows that in heat transfer, with the pioneering works of lewis and whitman in 1924 already proposing a mass transfer coefficient. Adsorption ch 12 mass transfer to an interface absorption mass transfer to another phase gas or liquid adsorption molecular onto solid surface porous solids provide high surface area per weight porous nanoparticles are ideal gas applications adsorption a.
Distillation column, dryer, steam distillation apparatus, dryer, adsorption column list of open source softwarelearning website. An industrial wastewater contains 10 mgl chlorophenol. This is accurately and easily measured for true cylindrical pellets and beads, but is. The model describes mass transfer as a pseudosteady state diffusion process through a flat film of thickness equal to one fifth of the particle radius. This course will provide an overview on mass transfer at basic to an intermediate level. Chapter 3 design of adsorption process rice university.
The species transferred to the liquid phase are referred to as solutes or absorbate. For example, in figure 4, the masstransfer rate for curve 2 is higher than the rate for curve 1, and the increase in adsorbate concen 1 the. A narrow mass transfer zone makes efficient use of the adsorbent. The desoprtion process can have a shock if the isotherm has a slope that is not monotonically decreasing. A model based on the ldf approximation for the mass transfer, considering the energy and momentum balances, was used to describe the adsorption. Iperrys chemical engineers handbook, 8th edition, chapter 22 irichardson and harker, \chemical engineering, volume 2, 5th edition, chapter 17 ischweitzer, \handbook of separation techniques for. Feb 14, 2015 department of applied chemistryadsorption.
Absorption, distillation, extraction, adsorption, drying. The shape of the mass transfer zone depends on the adsorption isotherm equilibrium expression, flow rate, and the diffusion characteristics. Mod04 lec01 introduction to absorption and solvent selection. In order to inherently account for the proper stoichiometry, this is most typically written as a mole balance. Mass transfer to buy postal correspondence package call at 09990657855.
The length of the masstransfer zone or, equivalently, the difference between breakthrough and equilibration times, depends on the masstransfer rate. The determination of rate controlling step in the process is important in the design of the process. The bed or bulk density is the mass of adsorbent in a specific volume. The adsorption equilibrium and breakthrough curves were determined at different temperatures 306 k, 323 k, 373 k and 423 k. Iperrys chemical engineers handbook, 8th edition, chapter 22. Chemical and biomolecular engineering clarkson university heat transfer is the study of december 29th, 2018 nptel mechanical engineering heat and mass transfer. Gas absorption essentially involved the transfer of materials from the gas phase to the liquid phase. Basics slide 3 a mass transfer process which involves the accumulation of substance at the interface of the two phases, such as, liquidliquid, gasliquid, gassolid, or liquidsolid interface or adhesion of atoms, ions, or molecules from a gas, liquid, or dissolved solid to a surface adsorbate the. The adsorption is the process of accumulating substances that are in solution on a suitable interface. Thus, most research on this kind of system is related to the evaluation of the adsorption and physicalchemical properties of the working. Developing a model for mass transfer in adsorption packedbed. Other mass transfer operations include distillation, humidification, liquidliquid extraction, adsorption and ion exchange, and so on. The common denominator in mass transfer processes is that species fluxes occur within a phase when there are compositionvariations within that phase. Therefore, in the present work, mass transfer studies were done to evaluate the ratelimiting step in the adsorption of phenol from aqueous solution onto lantana camara.
Mass transfer studies on adsorption of phenol from. Therefore, mass transfer conditions will also affect heat exchange, heat balance, and operating temperature. The cost and design of this treatment needs to be evaluated. Mandal, department of chemical engineering, iit guwahati. Adsorption equilibria, calculations for vapor, gas and liquid adsorptions. Drying curves treybal, mass transfer operations 667670 5. Understanding of mass transfer resistance for the adsorption. Complete study of breakthrough curve for designing. Unesco eolss sample chapters chemical engineeering and chemical process technology vol. Adsorption is one of the important treatment methods for the removal of pollutants from wastewater. Calculate the carbon requirement for a a single, mixed contactor cmfr b two mixed cmfr contactors in series c a column contactor.
Adsorption, definition and industrial application, types of adsorption, nature of commonly used adsorbents, adsorption equilibria, single gases and vapors, adsorption hysterises, effect of temperature on adsorption, heat of adsorption, adsorption of solute from dilute liquid solution, adsorption from concentrated solutions, material balance and freundlichs. Adsorption calculations using the film model approximation. Nptel syllabus mass transfer operations i web course course outline the importance of mass transfer operations in chemical processes is insightful. Design of packed column absorber based on the individual mass transfer coefficient duration. Quiz and multiple choice questions on mass transfer.
Experiments in laboratory scale are needed in order to scale up the results. Adsorption is the process in which atoms, ions or molecules from a substance it could be gas, liquid or dissolved solid adhere to a surface of the adsorbent. Complete study of breakthrough curve for designing adsorptive column. Diffusion, ficks first law, mass transfer coefficients, film theorysurface renewal theoryboundary layer theory. Adsorption equilibrium data are commonly gathered at a fixed temperature and plotted or. The mass flux of species i is defined as the mass of species i that pass through a unit. However, in both absorption and stripping operations, the columns are simpler than the distillation column. In some systems, additional forces bind absorbed molecules to the solid surface. Chemical engineering mass transfer operations i nptel. Mass transfer traditionally follows and builds upon that of and not upon fluid heat transfer. An industrial wastewater contains 10 mgl chlorophenol, and is going to be treated by carbon adsorption. Information on key topics will be provided in the form of summary of lecture notes, problems and adequate references. The basic principle of operation for carbon adsorption is the mass transfer and adsorption of. Comparison of batch and column adsorption study is mentioned.
In this manner, the masstransfer zone progresses along the length of the bed and an increasing portion of the bed becomes used or inactive. The following section consists of chemistry multiple choice questions on mass transfer. Nov 30, 2018 42 videos play all mass transfer operations i nptel iit guwahati lec 21. Gaitonde, department of mechanical engineering, iit bombay. Developing a model for mass transfer in adsorption packed. Absorption, liquidliquid extraction, separation processes, phase equilibrium, mass transfer, packed tower, plate tower, membrane contactor. Nptel chemical engineering mass transfer operations i ch303 mass transfer operations i.